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141.
A remarkable invariance in the ratio of 1,3-dimethylcarbazole (DMC) to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate. 相似文献
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Response of active tectonics on the alluvial Baghmati River, Himalayan foreland basin, eastern India 总被引:1,自引:2,他引:1
Active tectonics in a basin plays an important role in controlling a fluvial system through the change in channel slope. The Baghmati, an anabranching, foothills-fed river system, draining the plains of north Bihar in eastern India has responded to ongoing tectonic deformation in the basin. The relatively flat alluvial plains are traversed by several active subsurface faults, which divide the area in four tectonic blocks. Each tectonic block is characterized by association of fluvial anomalies viz. compressed meanders, knick point in longitudinal profiles, channel incision, anomalous sinuosity variations, sudden change in river flow direction, river flow against the local gradient and distribution of overbank flooding, lakes, and waterlogged area. Such fluvial anomalies have been identified on the repetitive satellite images and maps and interpreted through DEM and field observations to understand the nature of vertical movements in the area. The sub-surface faults in the Baghmati plains cut across the river channel and also run parallel which have allowed us to observe the effects of longitudinal and lateral tilting manifested in avulsions and morphological changes. 相似文献
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Paul J. Sylvester 《Geostandards and Geoanalytical Research》2005,29(1):41-52
This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis. 相似文献
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电子探针化学测年技术及其在地学中的应用 总被引:2,自引:0,他引:2
电子探针主要应用于固体无机材料的微区化学成分定量测定和表面形貌研究。近十年来电子探针化学测年技术发展迅速,并取得了丰富的研究成果。本文在简单介绍该技术发展历程后,进一步详细介绍该技术的基本原理、样品制备与分析、年龄计算方法等内容,最后讨论了该技术的优缺点,同时指出电子探针测年技术在地学中的具有广泛的应用前景。 相似文献
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松花江上游地区汞污染的化学生态效应 总被引:5,自引:0,他引:5
采样分析了吉林省东部松花江上游金矿开采区及其附近水、土壤、动植物及河流沉积物样品中汞的含量,发现河流沉积物中汞的污染相当严重;受其影响当地的植物和两栖类动物——中国林蛙体内总汞和甲基汞含量也明显高于对照组。实验表明,林蛙内脏对汞的富集能力大于肌肉;秋季对汞的富集大于春季;河流沉积物中甲基汞的含量与林蛙体内甲基汞的含量有较好的正相关。汞污染的来源与区域内个体金矿的滥采滥排有直接关系,表明人类活动所产生的有毒重金属在地表过程中出现了化学生态效应。 相似文献